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ThermoLab · Chapter 4

Energy integrals for closed systems

Integrates Cp(T), computes Δh and Δu, and evaluates polytropic boundary work.

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Detailed calculation reportEquations · substitution · verification

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13 linked modules on a single calculation base

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Engineering framework

Theory, equations and conditions of use

With a temperature-dependent Cp, the energy change is the area under the curve. Integration avoids assuming a constant specific heat outside a narrow range.

Fundamento

Enthalpy change

The molar integral is divided by the molar mass to give a mass basis.

\(\Delta h=\int_{T_1}^{T_2}c_p(T)\,dT\)

Fundamento

Simpson's rule

For an even number of subintervals, it weights the nodes 1-4-2-…-4-1.

\(I\approx\frac{\Delta T}{3n}[f_0+4f_1+2f_2+\cdots+f_n]\)

Fundamento

Boundary work

In a polytropic process P Vⁿ = constant, the work integrates in closed form.

\(W_b=\frac{P_2V_2-P_1V_1}{1-n}\)
Base documentalÇengel & Boles, 7th edition · SI appendices A-1 to A-28
USCS conversionA-1E to A-27E, via exact factors from the SI base
AlcancePreliminary design, teaching and independent verification

Engineering FAQ

Preguntas frecuentes

How many subintervals does Simpson's rule use?+

The engine uses 100, an even number that is sufficient for these smooth polynomials.

What happens if n=1?+

The isothermal form W=P₁V₁ ln(V₂/V₁) applies.

Are Δu and Δh the same?+

No. For an ideal gas, Δu=Δh-RΔT.

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